Blog20210131 のバックアップ差分(No.1)

#author("2021-01-30T19:05:01+09:00","default:ishikawa","ishikawa")
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2021年1月31日　論文

--CLAS

Chemical looping ammonia synthesis (hereafter referred to as CLAS) decouples the overall ammonia synthesis reaction into several step-wise reactions

With regard to the CLAS with H2 as the hydrogen source, there are two types of nitrogen carriers reported so far, i.e., transition metal nitrides (denoted as TMNs) and alkali or alkaline earth metal imides (denoted as ANHs), respectively.

Schematic diagram of CLAS mediated by the MnNx–ANH composite N carrier. AH stands for LiH or BaH2, and ANH stands for Li2NH or BaNH.

DOI: 10.1039/d0ta10519h

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--Radical and non-radical reactions

Cobalt Single Atoms Embedded in Nitrogen-Doped Graphene for Selective Oxidation of Benzyl Alcohol by Activated Peroxymonosulfate

DOI: 10.1002/smll.202004579

the dynamically catalytic effect of single cobalt atoms embedded in nitrogen-doped graphene for selective oxidation of BzOH by activated peroxymonosulfate.

The incorporated Co atoms function as active sites for Peroxymonosulfate (PMS) activation via both radical and non-radical pathways.

reactive •OH, SO4•−, and SO5•− radicals

the catalyst-mediated electron transfer by surface complexed substrate/PMS and the singlet oxygen ($SUP{1};O$SUB{2};).

if the 1O2 is able to induce the non-radical oxidation of BzOH, BzH can also be oxidized by 1O2.

メモ　他にも沢山出ていることが判明．

---Almost 100% Peroxymonosulfate Conversion to Singlet Oxygen on Single-Atom CoN2+2 Sites

DOI:10.1002/anie.202014472

---Oxidation of Benzyl Alcohol Compounds in the Presence of Carbon Hybrid Supported Platinum Nanoparticles (Pt@CHs) in Oxygen Atmosphere

DOI: 10.1038/s41598-020-62400-5

---Pt@CHs catalyst was carried out under molecular oxygen and at 80 °C.

Nonradicals induced degradation of organic pollutants by peroxydisulfate (PDS) and peroxymonosulfate (PMS): Recent advances and perspective

DOI: 0.1016/j.scitotenv.2020.142794

---Selective oxidation of benzyl alcohol to benzaldehyde with hydrogen peroxide over tetra-alkylpyridinium octamolybdate catalysts

DOI: 10.1039/b700534b (2007)


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--Polyazanes

Synthesis and Properties of Higher Nuclearity Polyazanes

DOI: 10.1002/chem.202004830

polyazanes are a new class of nitrogen-containing molecules that until now had not been considered as a
family with similar properties. We showed that this is indeed the case, as similarly substituted polyazanes with growing numbers of linked nitrogen atoms gradually fold to form helices and become increasingly less oxidizable.

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Molecular Mechanism for the Self-Supported Synthesis of Graphitic Carbon Nitride from Urea Pyrolysis

DPO: 10.1021/acs.jpclett.0c03559

(i) the synthesis of g-C3N4 monolayers does require intermediate linear melon structures, or inversely,

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Challenges in Controlled Thermal Deposition of Organic Diradicals

DOI: 10.1021/acs.chemmater.0c03880

it is possible to evaporate diradicals in a controlled environment obtaining thin films in which the diradical character is preserved.

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Defective Nanographenes Containing Seven-Five-Seven (7−5−7)-Membered Rings

DOI: 10.1021/jacs.0c12116

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Charge-Assisted Engineering of Color Centers in Diamond

DOI: 10.1002/pssa.202000614

the way to an advanced engineering of single defects in the solid-state

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RF discharge diagnostics: Some problems and their resolution

J. Appl. Phys. 129, 041101 (2021); [[link:https://doi.org/10.1063/5.0024258]]

 “The supreme judge of any physics theory is the experiment. Without experiments theoreticians turn sour” - Lev Landau

物理学の理論の最高裁判所は実験である。実験がなければ，理論家はいても意味がない。－レフ・ダヴィドヴィッチ・ランダウ

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Van Allen radiation belts

Energization to ultrarelativistic energies　（粒子の速度が光速に近いとき）

plasma number density drops down to very low values (~10 cm–3).

Allison et al., Sci. Adv. 2021; 7 : eabc0380 DOI: 10.1126/sciadv.abc0380

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Improving the Level of the Tyrosine Biosynthesis Pathway in Saccharomyces cerevisiae through HTZ1 Knockout and Atmospheric and Room Temperature Plasma (ARTP) Mutagenesis

DOI: 10.1021/acssynbio.0c00448

Atmospheric and room temperature plasma (ARTP) mutagenesis can induce breakage in plasmid DNA and oligonucleotides through treatment with a diverse range of plasma doses. (15 Appl. Microbiol. Biotechnol. 98, 5387−5396.)

NK-B2 was subsequently used as the starting strain to further enhance the production of tyrosine by ARTP mutagenesis.

Under the reaction catalyzed by tyrosine hydroxylase and DOPA dioxygenase (DOD), betalamic acid is converted from tyrosine, and finally, betaxanthins are produced through a spontaneous reaction between free
amines or amino acids and betalamic acid. (48 Plant Cell Physiol. 50, 1012−1016.; 49 Trends Plant Sci.
18, 334−343. )

メモ：チロシン　C9H11NO3，ベタラミン酸　C9H9NO5

Samples were treated with a helium plasma jet at 115 W RF power input and 10 standard liter per minute (SLM) gas flow; the plasma torch nozzle exit and the sample plate were 2 mm apart.

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Mass Fabrication of 3D Silicon Nano-/Microstructures by Fab-Free Process Using Tip-Based Lithography

DOI: 10.1002/smll.202005036

scanning probe lithography (SPL) combined with metal-assisted chemical etching (MACE)

dip-pen nanolithography (DPN) with polymer or by nanoshaving alkanethiol self-assembled monolayers (SAMs)

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anilox roll アニロックス　輪転印刷機のローラーに小さなインクを溜めるセルができたもの　（参照　フレキソ印刷）